Using sunlight to turn two greenhouse gases into valuable chemicals

91³Ō¹Ļ researchers have harnessed the power of sunlight to transform two of the most harmful greenhouse gases into valuable chemicals. The discovery could help combat climate change and provide a more sustainable way to produce certain industrial products.
āImagine a world where the exhaust from your car or emissions from a factory could be transformed, with the help of sunlight, into clean fuel for vehicles, the building blocks for everyday plastics, and energy stored in batteries,ā said co-first author Hui Su, a Postdoctoral Fellow in 91³Ō¹Ļās Department of Chemistry. āThatās precisely the kind of transformation this new chemical process enables.ā
The research teamās new light-driven chemical process converts methane and carbon dioxide into green methanol and carbon monoxide in one reaction. Both products are highly valued in the chemical and energy sectors, the researchers said.
Turning to nature for a sustainable solution
, published in Nature Communications, describe a novel mechanism rooted in natureās own blueprint, similar to how photosynthesis enables plants to convert carbon dioxide and water into glucose and oxygen using sunlight.
In this chemical process, a unique mix of gold, palladium and gallium nitride acts as a catalyst. When exposed to sunlight, the substance triggers a reaction: an oxygen atom from carbon dioxide attaches to a methane molecule, producing green methanol. Carbon monoxide is created as a byproduct.
āBy tapping into the abundant energy of the sun, we can essentially recycle two greenhouse gases into useful products. The process works at room temperature and doesnāt require the high heat or harsh chemicals used in other chemical reactions,ā said lead author Chao-Jun Li, a Distinguished James 91³Ō¹Ļ Professor in 91³Ō¹Ļās Department of Chemistry and a Canada Research Chair in Green/Organic Chemistry.
āThis innovation offers a promising path towards Canadaās target of net-zero emissions by 2050 and turns an environmental challenge into an opportunity for a more sustainable future,ā said co-first author Jing-Tan Han, a PhD student in 91³Ō¹Ļās Department of Chemistry.
The study was supported by the Natural Sciences and Engineering Research Council of Canada, the Canada Research Chair program, Fonds de Recherche du QuĆ©bec Nature et technologies, the Canada Foundation for Innovations, 91³Ō¹Ļās MSSI fund, Axelys and Catalum Technologies.